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Dealloying, Selective Leaching & Graphic Corrosion
What causes dealloying? Different metals and alloys have different electrochemical potentials (or corrosion potentials) in the same electrolyte. Modern alloys contain a number of different alloying elements that exhibit different corrosion potentials. The potential difference between the alloying elements is the driving force for the preferential attack on the more "active" element in the alloy. In the case of dezincification of brass, zinc is preferentially leached out of the copper-zinc alloy, leaving behind a copper-rich surface layer that is porous and brittle.